skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Anomalous behavior of the optical band gap of nanocrystalline zinc oxide thin films

Abstract

The optical band gap of ZnO films on fused silica in the carrier concentration regime of 10{sup 18}{endash}10{sup 20}/cm{sup 3} is reported. Contrary to theoretical predictions there is an anomalous increase in the band gap of ZnO films at a carrier concentration of 5{times}10{sup 18}/cm{sup 3}, followed by an abrupt decrease at a critical concentration of 3{endash}4{times}10{sup 19}/cm{sup 3} before the optical band gap rises again. Similar observations have been made before, but an explanation of these observations was lacking. We propose a model based on the existence of potential barriers at the grain boundaries, causing quantum confinement of the electrons in the small grains realized in these films. Quantum confinement leads to the initial rise in the optical band gap. On increasing the carrier concentration to the critical value the potentials at the grain boundaries collapse leading, to the abrupt decrease in the optical band gap. Above this carrier concentration the films behave according to existing many-body theories. {copyright} {ital 1997 Materials Research Society.}

Authors:
;  [1]
  1. Materials Department, College of Engineering, University of California, Santa Barbara, California 93106 (United States)
Publication Date:
OSTI Identifier:
508974
DOE Contract Number:  
FG03-91ER45447
Resource Type:
Journal Article
Journal Name:
Journal of Materials Research
Additional Journal Information:
Journal Volume: 12; Journal Issue: 6; Other Information: PBD: Jun 1997
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ZINC OXIDES; OPTICAL PROPERTIES; THIN FILMS; CHARGE CARRIERS; DOPED MATERIALS; BAND THEORY; ELECTRONIC STRUCTURE; ELECTRIC CONDUCTORS; GRAIN BOUNDARIES

Citation Formats

Srikant, V, and Clarke, D R. Anomalous behavior of the optical band gap of nanocrystalline zinc oxide thin films. United States: N. p., 1997. Web. doi:10.1557/JMR.1997.0193.
Srikant, V, & Clarke, D R. Anomalous behavior of the optical band gap of nanocrystalline zinc oxide thin films. United States. https://doi.org/10.1557/JMR.1997.0193
Srikant, V, and Clarke, D R. 1997. "Anomalous behavior of the optical band gap of nanocrystalline zinc oxide thin films". United States. https://doi.org/10.1557/JMR.1997.0193.
@article{osti_508974,
title = {Anomalous behavior of the optical band gap of nanocrystalline zinc oxide thin films},
author = {Srikant, V and Clarke, D R},
abstractNote = {The optical band gap of ZnO films on fused silica in the carrier concentration regime of 10{sup 18}{endash}10{sup 20}/cm{sup 3} is reported. Contrary to theoretical predictions there is an anomalous increase in the band gap of ZnO films at a carrier concentration of 5{times}10{sup 18}/cm{sup 3}, followed by an abrupt decrease at a critical concentration of 3{endash}4{times}10{sup 19}/cm{sup 3} before the optical band gap rises again. Similar observations have been made before, but an explanation of these observations was lacking. We propose a model based on the existence of potential barriers at the grain boundaries, causing quantum confinement of the electrons in the small grains realized in these films. Quantum confinement leads to the initial rise in the optical band gap. On increasing the carrier concentration to the critical value the potentials at the grain boundaries collapse leading, to the abrupt decrease in the optical band gap. Above this carrier concentration the films behave according to existing many-body theories. {copyright} {ital 1997 Materials Research Society.}},
doi = {10.1557/JMR.1997.0193},
url = {https://www.osti.gov/biblio/508974}, journal = {Journal of Materials Research},
number = 6,
volume = 12,
place = {United States},
year = {Sun Jun 01 00:00:00 EDT 1997},
month = {Sun Jun 01 00:00:00 EDT 1997}
}