Synthesis of BiPbSrCaCuO superconductor
Patent
·
OSTI ID:5078271
A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi[sub a]Pb[sub b]Sr[sub c]Ca[sub d]Cu[sub e]O[sub f] wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10[+-]z by reacting a mixture of Bi[sub 4]Sr[sub 3]Ca[sub 3]Cu[sub 4]O[sub 16[+-]z], an alkaline earth metal cuprate, e.g., Sr[sub 9]Ca[sub 5]Cu[sub 24]O[sub 41], and an alkaline earth metal plumbate, e.g., Ca[sub 2[minus]x]Sr[sub x]PbO[sub 4] wherein x is about 0.5, is disclosed.
- DOE Contract Number:
- W-7405-ENG-36
- Assignee:
- Dept. of Energy, Washington, DC (United States)
- Patent Number(s):
- US 5300486; A
- Application Number:
- PPN: US 8-067911
- OSTI ID:
- 5078271
- Resource Relation:
- Patent File Date: 27 May 1993
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
BISMUTH OXIDES
SYNTHESIS
CALCIUM OXIDES
COPPER OXIDES
LEAD OXIDES
STRONTIUM OXIDES
CHEMICAL COMPOSITION
HIGH-TC SUPERCONDUCTORS
ALKALINE EARTH METAL COMPOUNDS
BISMUTH COMPOUNDS
CALCIUM COMPOUNDS
CHALCOGENIDES
COPPER COMPOUNDS
LEAD COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
STRONTIUM COMPOUNDS
SUPERCONDUCTORS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
360201 - Ceramics
Cermets
& Refractories- Preparation & Fabrication
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
BISMUTH OXIDES
SYNTHESIS
CALCIUM OXIDES
COPPER OXIDES
LEAD OXIDES
STRONTIUM OXIDES
CHEMICAL COMPOSITION
HIGH-TC SUPERCONDUCTORS
ALKALINE EARTH METAL COMPOUNDS
BISMUTH COMPOUNDS
CALCIUM COMPOUNDS
CHALCOGENIDES
COPPER COMPOUNDS
LEAD COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
STRONTIUM COMPOUNDS
SUPERCONDUCTORS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
360201 - Ceramics
Cermets
& Refractories- Preparation & Fabrication