Mechanism of near-threshold stimulated desorption of protons from transition-metal surfaces
Journal Article
·
· Phys. Rev. Lett.; (United States)
The mechanism for near threshold electron and photon stimulated desorption of protons from transition-metal surfaces has been investigated with use of configuration-interaction techniques on finite clusters. The calculations indicate that the protons arise from repulsive states involving double excitations from the metal-hydrogen bonding orbitals and suggest that the process may occur via a surface predissociation mechanism. The calculations are compared to experimental electron stimulated desorption results for Ni<111>.
- Research Organization:
- Sandia National Laboratories, Livermore, California 94550
- OSTI ID:
- 5047485
- Journal Information:
- Phys. Rev. Lett.; (United States), Vol. 48:20
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
36 MATERIALS SCIENCE
DESORPTION
CONFIGURATION INTERACTION
NICKEL
SORPTIVE PROPERTIES
PROTONS
CORRELATIONS
ELECTRON COLLISIONS
EXPERIMENTAL DATA
PHOTONS
PREDISSOCIATION
THEORETICAL DATA
THRESHOLD ENERGY
BARYONS
COLLISIONS
DATA
DISSOCIATION
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
FERMIONS
HADRONS
INFORMATION
MASSLESS PARTICLES
METALS
NUCLEONS
NUMERICAL DATA
SURFACE PROPERTIES
TRANSITION ELEMENTS
360104* - Metals & Alloys- Physical Properties
DESORPTION
CONFIGURATION INTERACTION
NICKEL
SORPTIVE PROPERTIES
PROTONS
CORRELATIONS
ELECTRON COLLISIONS
EXPERIMENTAL DATA
PHOTONS
PREDISSOCIATION
THEORETICAL DATA
THRESHOLD ENERGY
BARYONS
COLLISIONS
DATA
DISSOCIATION
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
FERMIONS
HADRONS
INFORMATION
MASSLESS PARTICLES
METALS
NUCLEONS
NUMERICAL DATA
SURFACE PROPERTIES
TRANSITION ELEMENTS
360104* - Metals & Alloys- Physical Properties