Electrochemical polymerization of pyrrole derivatives

Conference · Fri Jan 01 00:00:00 EST 1988

OSTI ID:5026592

Inagaki, T; Hunter, M; Yang, X Q; Skotheim, T A; Lee, H S; Okamoto, Y

Electrochemical copolymerization of pyrrole and 3-(6-ferrocenyl-6-hydroxyhexyl)pyrrole (P-Fc) yields a ferrocene functionalized polypyrrole with a controlled amount of ferrocene functionalization. Similarly, copolymers of pyrrole and 3-(4-(2,5- dimethoxyphenyl)butyl)pyrrole (P-MP) can be made by electrochemical polymerization and converted to the copolymers containing pH dependent electroactive hydroquinone moieties. 16 refs., 6 figs.

• Research Organization: Brookhaven National Lab., Upton, NY (USA)
• DOE Contract Number: AC02-76CH00016
• OSTI ID: 5026592
• Report Number(s): BNL-41198; CONF-8710283-4; CONF-8710283-; ON: DE88010661
• Resource Relation: Conference: Symposium on electroresponsive polymers, Upton, NY, USA, 4 Oct 1987
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
FERROCENE
COPOLYMERIZATION
IRON COMPLEXES
PYRROLES
COPOLYMERS
ELECTROCHEMISTRY
FILMS
PH VALUE
VOLTAMETRY
AZOLES
CHEMICAL REACTIONS
CHEMISTRY
COMPLEXES
DIENES
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC POLYMERS
POLYENES
POLYMERIZATION
POLYMERS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties