Synthesis of nitrogen-containing heterocycles of an iron catalyst. 2. The conversions of 1,4-butanediol and diethylene glycol in the presence of ammonia and hydrogen

Journal Article · Sat Aug 01 00:00:00 EDT 1987 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00663853· OSTI ID:5022893

Kliger, G A; Lesik, O A; Marchevskaya, E V; Mikaya, A I; Zaikin, V G; Glebov, L S; Loktev, S M

The gas-phase interaction of 1,4-butanediol and diethylene glycol with ammonia and/or hydrogen on a reduced, fused, iron catalyst has been investigated. We carried out the investigation in a high-pressure, laboratory flow apparatus. We fed into the reactor, at the necessary rate, a previously heated, gaseous mixture of diol, NH/sub 3/, and H/sub 2/. The reaction products formed, along with unreacted diol, were condensed in a condenser-separator. The compounds obtained were analyzed by GLC on a Chrom-5 chromatograph. We carried out the identification of the catalysate components by a chromatography-mass spectrometric technique.

• Research Organization: A. V. Topchiev Institute of Petrochemical Synthesis, Moscow (USSR)
• OSTI ID: 5022893
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Vol. 23:2; Other Information: Translated from Khim. Geterotsikl. Soedin.; 23: No. 2, 195-198(Feb 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMINES
SYNTHESIS
BUTANEDIOLS
HETEROGENEOUS CATALYSIS
GLYCOLS
HETEROCYCLIC COMPOUNDS
IRON
CATALYTIC EFFECTS
ACTIVATION ENERGY
AMMONIA
CATALYSTS
CHROMATOGRAPHY
HYDROGEN
MASS SPECTRA
MATERIALS TESTING
STRUCTURAL CHEMICAL ANALYSIS
ALCOHOLS
CATALYSIS
ELEMENTS
ENERGY
HYDRIDES
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
METALS
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NONMETALS
ORGANIC COMPOUNDS
SEPARATION PROCESSES
SPECTRA
TESTING
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties