Synthesis and characterization of new copper-chromium layered double hydroxides pillared with polyoxovanadates
Journal Article
·
· Journal of Solid State Chemistry
- Universite Blaise Pascal, Aubiere (France); and others
In this study, the authors have focused on the intercalation by ion-exchange of some polyoxovanadate anions from aqueous solution (decavanadate V{sub 10}O{sub 28{sup 6-}}, tetravanadate V{sub 4}O{sub 12}{sup 4-}, and pyrovanadate V{sub 2}O{sub 7}{sup 4-}) into the layers of a copper chromium hydrotalcite-like compound, PXRD, FTIR, TGA, and EXAFS studies have provided information about the specific oxovanadate ions in the interlayers and their orientation. Thermal treatment of these LDHs was also examined. A grafting process of pyrovanadate anions onto the hydroxylated sheets has been demonstrated at room temperature.
- OSTI ID:
- 478814
- Journal Information:
- Journal of Solid State Chemistry, Vol. 126, Issue 2; Other Information: PBD: 1 Nov 1996
- Country of Publication:
- United States
- Language:
- English
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