The dynamics of surface-catalyzed reactions studied by infrared chemiluminescence of the CO and CO{sub 2} products

Conference · Tue Dec 31 00:00:00 EST 1996

OSTI ID:468022

Watanabe, K; Uetsuka, H; Ohnuma, H; Kunimori, K ^[1]

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1. Univ. of Tsukuba, Ibaraki (Japan)

The infrared chemiluminescence technique has been applied to the selective formation of syngas (CO + H{sub 2}) from the oxidation of small alkanes on Pt, the decomposition and oxidation of CH{sub 3}OH and HCOOH on Pt and Ni, and CO oxidation on Pd(111) and Pd(110). The different internal (vibrational and rotational) energy states of the CO and CO{sub 2} products have been observed, which reflect the difference in the dynamics of these reactions.

• OSTI ID: 468022
• Report Number(s): CONF-960652-; TRN: 96:004817-0059
• Resource Relation: Conference: 11. international congress on catalysis (ICC-11), Baltimore, MD (United States), 30 Jun - 5 Jul 1996; Other Information: PBD: 1996; Related Information: Is Part Of 11th International congress on catalysis - 40th anniversary. Part A and B; Hightower, J.W.; Delgass, W.N.; Iglesia, E.; Bell, A.T. [eds.]; PB: 1482 p.
• Country of Publication: United States
• Language: English

Related Subjects

10 SYNTHETIC FUELS
03 NATURAL GAS
SYNTHESIS GAS
CHEMICAL PREPARATION
PLATINUM
CATALYTIC EFFECTS
NICKEL
PALLADIUM
BUTANE
OXIDATION
METHANE
PARTIAL OXIDATION PROCESSES
ALKANES
CHEMILUMINESCENCE
TEMPERATURE DEPENDENCE