FTIR analysis of Smoky Mountain aerosol
- Rutgers Univ., New Brunswick, NJ (United States)
As part of the Southeastern Aerosol and Visibility Study in the Smoky Mountains (July 15-August 25, 1995), we collected samples on ZnSe discs in a Hering Low Pressure Impactor (LPI) from 7am-7pm daily. Impactor size cuts were 2.0, 1.0, 0.50, 0.26, 0.12, 0.05 um. Samples, blanks, and polystyrene standards were analyzed in a Mattson Research Series 100 FTIR Spectroscope. After initial, non-destructive analysis, a subset of samples were gently rinsed with hexane, acetone, and water in succession and analyzed by FTIR after each rinse. Sulfate and carbonyl were consistently observed in sub-micron particles, and commonly detected with soil dust in the 1-2 um size fraction. Carbonyl is associated with secondary organic aerosol formation. Aliphatics in the Smoky Mountain aerosol were most prevalent in the 1-2 um size fraction, suggesting a primary biogenic origin (e.g., plant waxes and organic acids). This contrasts with aliphatic size distributions in Los Angeles aerosols, which peaked below 0.12 um, and were attributed to automotive emissions.
- OSTI ID:
- 466167
- Report Number(s):
- CONF-9606185-; TRN: 96:005931-0118
- Resource Relation:
- Conference: 5. international conference on atmospheric sciences and applications to air quality, Seattle, WA (United States), 18-20 Jun 1996; Other Information: PBD: 1996; Related Information: Is Part Of The 5th international atmospheric sciences and applications to air quality conference; PB: 322 p.
- Country of Publication:
- United States
- Language:
- English
Similar Records
Characterization of the aerosol in the Great Smoky Mountains
Relationship of liquefaction behavior of a set of high-sulfur coals to chemical structural characteristics