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Title: Effects of substrate mineralogy on the biodegradability of fuel components

Journal Article · · Environmental Toxicology and Chemistry
 [1];  [2]
  1. Naval Command, Control and Ocean Surveillance Center, San Diego, CA (United States)
  2. Computer Sciences Corp., San Diego, CA (United States)

Experiments were carried out to determine the effects of mineralogy on the biodegradability of components of a whole fuel by a soil microbial consortium. Samples of quartz sand (Fischer Sea Sand) and illite clay (API 35) were spiked with marine diesel fuel, aged, slurried, and inoculated, and concentrations of fuel components were monitored over time. To help distinguish biotic from abiotic processes, identical samples were poisoned with mercuric chloride and were run in parallel. While there was a chromatographic and biomarker evidence of n-alkane biodegradation in the sand samples, illite samples showed no evidence of biogenic loss of aliphatic components. Polycyclic aromatic hydrocarbons, on the other hand, were lost equivalently on both minerals and in both cases were lost to a much greater extent than were total petroleum hydrocarbons (TPHs). These results suggest that under experimental conditions, illite inhibited the bioavailability of some TPH components to the soil microbial consortium.

Sponsoring Organization:
USDOE
OSTI ID:
464867
Report Number(s):
CONF-9504283-; ISSN 0730-7268; TRN: 97:007403
Journal Information:
Environmental Toxicology and Chemistry, Vol. 15, Issue 11; Conference: Department of Defense tri-service workshop on bioavailability of organic contaminants in soils and sediments, Monterey, CA (United States), 9-12 Apr 1995; Other Information: PBD: Nov 1996
Country of Publication:
United States
Language:
English