Estimation of Arrhenius parameters for the 1,1 elimination of H{sub 2} from Si{sub 2}H{sub 6} and the role of chemically activated disilane in silane pyrolysis
Journal Article
·
· Journal of Physical Chemistry
- Univ. of Minnesota, Minneapolis, MN (United States)
This paper analyzes the Arrhenius parameters for the 1,1 H{sub 2} dissociation channel reaction rate for the disilane thermal decomposition. The RRKM model is used to estimate these arrhenius parameters. The role that chemically active disilane plays in the pyrolysis of silanes is also discussed. The estimate of the heat of formation of H{sub 3}SiSiH is determined also.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 456989
- Journal Information:
- Journal of Physical Chemistry, Vol. 96, Issue 19; Other Information: PBD: 17 Sep 1992
- Country of Publication:
- United States
- Language:
- English
Similar Records
Rice-Ramsperger-Kassel-Marcus theoretical prediction of high-pressure arrhenius parameters by nonlinear regression: application to silane and disilane decomposition
Estimation of the Arrhenius parameters for SiH sub 4 l reversible SiH sub 2 + H sub 2 and. Delta. H sub f degree (SiH sub 2 ) by a nonlinear regression analysis of the forward and reverse reaction rate data
Determination of the arrhenius parameters for Si{sub 2}H{sub 6} {l_reversible} SiH{sub 4} + SiH{sub 2} and {Delta}H{degrees} {sub f}(SiH{sub 2}) by RRKM analysis of forward and reverse reaction rate data
Journal Article
·
Thu Oct 22 00:00:00 EDT 1987
· J. Phys. Chem.; (United States)
·
OSTI ID:456989
Estimation of the Arrhenius parameters for SiH sub 4 l reversible SiH sub 2 + H sub 2 and. Delta. H sub f degree (SiH sub 2 ) by a nonlinear regression analysis of the forward and reverse reaction rate data
Journal Article
·
Thu Jan 10 00:00:00 EST 1991
· Journal of Physical Chemistry; (USA)
·
OSTI ID:456989
Determination of the arrhenius parameters for Si{sub 2}H{sub 6} {l_reversible} SiH{sub 4} + SiH{sub 2} and {Delta}H{degrees} {sub f}(SiH{sub 2}) by RRKM analysis of forward and reverse reaction rate data
Journal Article
·
Thu Sep 17 00:00:00 EDT 1992
· Journal of Physical Chemistry
·
OSTI ID:456989