Curing and toughening of epoxy resins with phosphorus containing monomers and polymers
- Kwangji Inst. of Science and Technology, Kwangju (Korea, Republic of); and others
Epoxy resins have been utilized in many areas, from house holds to airplanes, for the past several decades due to some exceptional properties such as low cost, good mechanical properties and excellent adhesive properties. However, low fracture toughness and flame resistance of epoxy resins have limited their applicability. Therefore, enhancing those properties have been of great interest to many researchers and scientists. As introduced by McGrath and co-workers in 1980s, the reactive thermoplastic polymers have proven to be an excellent toughener for improving not only fracture toughness but also adhesive properties without sacrificing thermo-mechanical properties and chemical resistance. Flame retardency could be improved by adding flame retardent additives which are divided into two groups; additives and reactives. However, among the additives, halogen compounds are known to be toxic gas generator and ozone depleter. Moreover, additives could be potentially leached out of the material, while reactives are inferior to additives. Recently, a reactive type phosphine oxide containing flame retardants have been introduced by McGrath and co-workers and proven to be an excellent flame retardant. In this paper, phospine oxide containing monomers were prepared and utilized as curing agents for expoxy resins, and starting materials for the polymers.
- OSTI ID:
- 441503
- Report Number(s):
- CONF-960214-; TRN: 96:006556-0036
- Resource Relation:
- Conference: 19. annual meeting of the Adhesion Society, Inc, Myrtle Beach, SC (United States), 18-21 Feb 1996; Other Information: PBD: 1996; Related Information: Is Part Of Proceedings of the 19th annual meeting of the Adhesion Society; Ward, T.C. [ed.]; PB: 567 p.
- Country of Publication:
- United States
- Language:
- English
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