Stabilized matrix for molten carbonate fuel cell

Conference · Tue Dec 31 00:00:00 EST 1996

OSTI ID:435565

Nirasawa, Hitoshi; Kawachi, Takanori; Ogawa, Takashi; Hori, Michio; Tomimatsu, Norihiro; Nakagawa, Kazuaki; Ohzu, Hideyuki ^[1]; Yamazaki, Yohtaro ^[2]

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1. Toshiba R and D Center, Kawasaki (Japan)
2. Tokyo Inst. of Tech., Yokohama (Japan). Graduate School at Nagatsu

For commercialization of molten carbonate fuel cell (MCFC) power plants, the most important factors are MCFC performance and life. The performance and life of an MCFC depend on the electrolyte loss and gas crossover due to the matrix degradation, such as LiAlO{sub 2} particle growth during cell operation and the matrix cracking at the initial heat-up stage. In order to suppress the matrix degradation, the authors fabricated a stabilized matrix with {alpha}-LiAlO{sub 2} as the electrolyte support material and with long {alpha}-Al{sub 2}O{sub 3} fibers as the reinforcement. They assembled the cell with the stabilized matrix. The performance of the cell is stable for 7,000 hours. They consider that the matrix degradation, such as the particle growth during cell operation and matrix cracking, has not occurred in this cell.

• OSTI ID: 435565
• Report Number(s): CONF-960805-; TRN: IM9710%%223
• Resource Relation: Conference: 31. intersociety energy conversion engineering conference, Washington, DC (United States), 9-14 Aug 1996; Other Information: PBD: 1996; Related Information: Is Part Of Proceedings of the 31. intersociety energy conversion engineering conference. Volume 2: Conversion technologies, electro-chemical technologies, Stirling engines, thermal management; Chetty, P.R.K.; Jackson, W.D.; Dicks, E.B. [eds.]; PB: 867 p.
• Country of Publication: United States
• Language: English

Related Subjects

30 DIRECT ENERGY CONVERSION
MOLTEN CARBONATE FUEL CELLS
MATRIX MATERIALS
PERFORMANCE
SERVICE LIFE
LITHIUM OXIDES
ALUMINIUM OXIDES
STABILITY
THERMAL DEGRADATION
MATERIALS TESTING