Field demonstration of on-site analytical methods for TNT and RDX in ground water
- Environmental Protection Agency Region 10, Portland, OR (United States)
- Black and Veatch Special Projects Corp., Tacoma, WA (United States)
- Naval Research Lab., Washington, DC (United States). Center for Bio/Molecular Science and Engineering
- Army Corps of Engineers, Hanover, NH (United States). Cold Regions Research and Engineering Lab.
A field demonstration was conducted to assess the performance of eight commercially-available and emerging colorimetric, immunoassay, and biosensor on-site analytical methods for explosives 2,4,6-trinitrotoluene (TNT) and hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) in ground water and leachate at the Umatilla Army Depot Activity, Hermiston, Oregon and US Naval Submarine Base, Bangor, Washington, Superfund sites. Ground water samples were analyzed by each of the on-site methods and results compared to laboratory analysis using high performance liquid chromatography (HPLC) with EPA SW-846 Method 8330. The commercial methods evaluated include the EnSys, Inc., TNT and RDX colorimetric test kits (EPA SW-846 Methods 8515 and 8510) with a solid phase extraction (SPE) step, the DTECH/EM Science TNT and RDX immunoassay test kits (EPA SW-846 Methods 4050 and 4051), and the Ohmicron TNT immunoassay test kit. The emerging methods tested include the antibody-based Naval Research Laboratory (NRL) Continuous Flow Immunosensor (CFI) for TNT and RDX, and the Fiber Optic Biosensor (FOB) for TNT. Accuracy of the on-site methods were evaluated using linear regression analysis and relative percent difference (RPD) comparison criteria. Over the range of conditions tested, the colorimetric methods for TNT and RDX showed the highest accuracy of the emerging methods for TNT and RDX. The colorimetric method was selected for routine ground water monitoring at the Umatilla site, and further field testing on the NRL CFI and FOB biosensors will continue at both Superfund sites.
- OSTI ID:
- 422834
- Report Number(s):
- CONF-9605266-; TRN: IM9707%%141
- Resource Relation:
- Conference: 9. Annual conference on hazardous waste remediation, Bozeman, MT (United States), 8-10 Jun 1994; Other Information: PBD: 1996; Related Information: Is Part Of Proceedings of the 1996 Hazardous Substance Research Center/Waste-management Education and Research Consortium joint conference on the environment; Erickson, L.E. [ed.] [Kansas State Univ., Manhattan, KS (United States)]; Grant, S.C. [ed.] [Haskell Indian Nations Univ., Lawrence, KS (United States)]; Tillison, D.L.; McDonald, J.P. [eds.]; PB: 706 p.
- Country of Publication:
- United States
- Language:
- English
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