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Title: Synthesis and characterization of lanthanide(III) (La, Gd, Yb, Y) disalicylidene-1,2-phenylenediamine (H{sub 2}dsp) Schiff-base complexes

Journal Article · · Inorganic Chemistry
;  [1]
  1. Univ. of Massachusetts, Amherst, MA (United States)

Novel rare earth (III) disalicylidene-1,2-phenylenediamine(H{sub 2}dsp) complexes with the formula M[Ln(dsp){sub 2}] (M = Li, Na, K, Cs) were prepared. UV-visible absorption and NMR were used to study the disproportionation equilibrium for these complexes in DMSO. Structures for these complexes are suggested.

Sponsoring Organization:
USDOE
OSTI ID:
420990
Journal Information:
Inorganic Chemistry, Vol. 33, Issue 23; Other Information: PBD: 9 Nov 1994
Country of Publication:
United States
Language:
English