Thermal decomposition of 2,4,6-trinitrotoluene in melt and solutions
Journal Article
·
· Russian Chemical Bulletin
- Institute of Chemical Physics, Moscow (Russian Federation)
Thermal decomposition of 2,4,6-trinitrotoluene in the temperature range from 200 to 340{degrees}C in melt and in solutions was studied. The main features of the process (high initial rates, activation energies lower than those in the gaseous phase, a higher acceleration at the catalytic stage, and the effect of nonpolar solvents on initial rates) are explained in terms of a kinetic scheme corresponding to a degenerate branched chain reaction.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 391790
- Journal Information:
- Russian Chemical Bulletin, Vol. 44, Issue 2; Other Information: PBD: Aug 1995; TN: Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya; No. 2, 266-271(Feb 1995)
- Country of Publication:
- United States
- Language:
- English
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