Preparation and characterization of transparent nanocrystalline TiO{sub 2} films possessing well-defined morphologies
- Univ. College Dublin (Ireland)
We describe the preparation, characterization, and potential-dependent optical absorption spectroscopy of transparent nanocrystalline TiO{sub 2} films possessing well-defined morphologies. Regarding preparation, Langmuir-Blodgett techniques are used to deposit between one and four monolayers of TiO{sub 2} nanocrystallites on conducting glass. As the average spacing between the nanocrystallites constituting a deposited monolayer may be controlled, the degree of nanoporosity of the resulting nanocrystalline film can be determined. Subsequent firing fuses the constituent crystallites of the deposited monolayers and ensures an ohmic contact with the conducting substrate. Characterization by electron microscopy and optical absorption spectroscopy has been undertaken. The former reveals the above films to be nanoporous or close-packed arrays of anatase nanocrystallites. The latter has allowed determination of an absorption coefficient for anatase at 326 nm. Measurement of potential-dependent optical absorption spectra has also proved possible. Results obtained suggest that the degree of charge accumulation possible at a given applied potential is dependent on the morphology of the nanocrystalline film. 20 refs., 9 figs.
- OSTI ID:
- 374470
- Journal Information:
- Journal of Physical Chemistry, Vol. 100, Issue 25; Other Information: PBD: 20 Jun 1996
- Country of Publication:
- United States
- Language:
- English
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