Hydroformylation catalyzed by immobilized rhodium complex to polymer support

Conference · Tue Oct 01 00:00:00 EDT 1996

OSTI ID:370711

Yoneda, N; Nakagawa, Y; Mimami, T ^[1]

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1. Chiyoda Corp., Yokohama (Japan)

The concept of hydroformylation by immobilized rhodium complexes on solid support has received a certain amount of attention, as revealed by many literature and patents. Polymers such as styrene-divinyl benzene and inorganic compounds functionalized by phosphine or amines have been used as supports. This study reports on the use of divinylbenzene crosslinked with vinyl pyridine as the support. Three types of rhodium complexes were prepared and their properties and activities for the hydroformylation of propylene and 1-octene were studied at 100-130{degrees}C, 30-90 Kg/cm{sup 2} and H{sub 2}/CO=1. This novel catalyst has both hydroformylation activity and insignificant rhodium leaching.

• OSTI ID: 370711
• Report Number(s): CONF-960376-; TRN: 96:003805-0771
• Resource Relation: Conference: Spring national meeting of the American Chemical Society (ACS), New Orleans, LA (United States), 24-28 Mar 1996; Other Information: PBD: 1996; Related Information: Is Part Of 211th ACS national meeting; PB: 2284 p.
• Country of Publication: United States
• Language: English

Related Subjects

02 PETROLEUM
40 CHEMISTRY
DIVINYLBENZENE
CROSS-LINKING
PROPYLENE
CARBONYLATION
RHODIUM COMPLEXES
CATALYTIC EFFECTS
PYRIDINES
AMINES
INORGANIC COMPOUNDS
POLYMERS
STYRENE
CATALYST SUPPORTS
PETROCHEMICALS