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Title: Crystallinity and magnetoresistance in calcium doped lanthanum manganites

Book ·
OSTI ID:323391
;  [1]
  1. Florida State Univ., Tallahassee, FL (United States)

Thin films of calcium doped lanthanum manganites La{sub 1{minus}x}Ca{sub x}MnO{sub 3} (LCMO) with x {approximately} 0.41 have been prepared on LaAlO{sub 3}(001) (LAO) Y-stabilized ZrO{sub 2}(001) (YSZ), and Al{sub 2}O{sub 3}(0001) (SAP) substrates by liquid delivery metal-organic chemical vapor deposition (LD-MOCVD). The films on YSZ and SAP substrates have a textured, polycrystalline morphology with a preferred orientation of (110). The films on LAO show a single-crystalline morphology and a (100) orientation. Transport measurements show the polycrystalline films have a resistance peak approximately 60 K lower than the films on LAO and, in general, have a much higher overall resistance. The magnetoresistance (MR) ratio ([R(H) - R(0)]/R(H)) is sharply peaked near the maximum in resistance for the films on LAO, while the polycrystalline films show a noticeable absence of this sharply peaked behavior and a flat, rather large ({approximately} 100%) MR ratio over a large temperature range. These results will be discussed in terms of grain boundary scattering, crystallite size, and magnetization.

OSTI ID:
323391
Report Number(s):
CONF-971201-; ISBN 1-55899-399-1; TRN: 99:004224
Resource Relation:
Conference: 1997 fall meeting of the Materials Research Society, Boston, MA (United States), 1-5 Dec 1997; Other Information: PBD: 1998; Related Information: Is Part Of Science and technology of magnetic oxides; Hundley, M.F. [ed.] [Los Alamos National Lab., NM (United States)]; Nickel, J.H. [ed.] [Hewlett-Packard Labs., Palo Alto, CA (United States)]; Ramesh, R. [ed.] [Univ. of Maryland, College Park, MA (United States)]; Tokura, Yoshinori [ed.] [Univ. of Tokyo (Japan)]; PB: 375 p.; Materials Research Society symposium proceedings, Volume 494
Country of Publication:
United States
Language:
English