Combustion chemistry of energetic materials studied by probing mass spectrometry
- Russian Academy of Sciences, Novosibirsk (Russian Federation). Inst. of Chemical Kinetics and Combustion
The methods of probing mass spectrometry (PMS) for diagnostic of flames and for the study of kinetics and mechanism of the thermal decomposition products of energetic materials (EM) are described. Several types of instruments based on microprobe and molecular beam mass spectrometric sampling have been developed. Time of flight mass spectrometer has been used. Apparatuses for high (10 atm) and low (<1 atm) pressure have been developed for the study of combustion and decomposition of EM by PMS ``in situ.`` Several examples are presented to demonstrate application of PMS method for the study of EM flame structure, thermal decomposition and dynamic of ignition. Experimental data on decomposition of double base propellants ammonium dinitramide, ammonium perchlorate are presented.
- OSTI ID:
- 248246
- Report Number(s):
- CONF-951155-; ISBN 1-55899-321-5; TRN: IM9628%%346
- Resource Relation:
- Conference: Fall meeting of the Materials Research Society (MRS), Boston, MA (United States), 27 Nov - 1 Dec 1995; Other Information: PBD: 1996; Related Information: Is Part Of Decomposition, combustion, and detonation chemistry of energetic materials; Brill, T.B. [ed.] [Univ. of Delaware, Newark, DE (United States)]; Russell, T.P. [ed.] [Naval Research Lab., Washington, DC (United States)]; Tao, W.C. [ed.] [Lawrence Livermore National Lab., CA (United States)]; Wardle, R.B. [ed.] [Thiokol Corp., Brigham City, UT (United States)]; PB: 469 p.; Materials Research Society symposium proceedings, Volume 418
- Country of Publication:
- United States
- Language:
- English
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