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Title: Photosensitive polymer systems based on iron, ruthenium, and osmium complexes with 5-chloro-1,10-phenanthroline

Abstract

The possibility of synthesis of polymers based on Fe(II), Ru(II), and Os(II) complexes with 5-chloro-1,10-phenanthroline (5Cl-phen) was demonstrated previously. It was shown that these polymeric complexes are photochemically active and possess electronic redox-conductivity and electrochromic properties. These compounds can be prepared by scanning of the platinum electrode potential from -0.7 to 1.7 V (vs. SCE) in acetonitrile solutions of corresponding monomers or with potentiostatic electrode polarization at -1.6 V. Optimal conditions of preparation of polymeric films based on the above complexes, the kinetics of their formation, data on stability, and parameters of electronic conductivity were presented previously. Here, the authors report the results of studies of the photosensitivity of electrodes modified with each component separately.

Authors:
; ;  [1]
  1. A.I. Gertsen Russian State Pedagogical Univ., St. Petersburg (Russian Federation)
Publication Date:
OSTI Identifier:
244013
Resource Type:
Journal Article
Journal Name:
Russian Journal of Applied Chemistry
Additional Journal Information:
Journal Volume: 68; Journal Issue: 2; Other Information: PBD: 10 Aug 1995; TN: Translated from Zhurnal Prikladnoi Khimii; 68: No. 2, 333-334(Feb 1995)
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; 36 MATERIALS SCIENCE; POLYMERS; PHOTOSENSITIVITY; IRON COMPLEXES; RUTHENIUM COMPLEXES; OSMIUM COMPLEXES; PHOTOCHEMICAL REACTIONS; PHENANTHROLINES; ELECTROCHEMISTRY; FILMS; CHEMICAL REACTION KINETICS; ELECTRIC CONDUCTIVITY; CHEMICAL PREPARATION

Citation Formats

Borisov, A N, Timonov, A M, and Shagisultanova, G A. Photosensitive polymer systems based on iron, ruthenium, and osmium complexes with 5-chloro-1,10-phenanthroline. United States: N. p., 1995. Web.
Borisov, A N, Timonov, A M, & Shagisultanova, G A. Photosensitive polymer systems based on iron, ruthenium, and osmium complexes with 5-chloro-1,10-phenanthroline. United States.
Borisov, A N, Timonov, A M, and Shagisultanova, G A. 1995. "Photosensitive polymer systems based on iron, ruthenium, and osmium complexes with 5-chloro-1,10-phenanthroline". United States.
@article{osti_244013,
title = {Photosensitive polymer systems based on iron, ruthenium, and osmium complexes with 5-chloro-1,10-phenanthroline},
author = {Borisov, A N and Timonov, A M and Shagisultanova, G A},
abstractNote = {The possibility of synthesis of polymers based on Fe(II), Ru(II), and Os(II) complexes with 5-chloro-1,10-phenanthroline (5Cl-phen) was demonstrated previously. It was shown that these polymeric complexes are photochemically active and possess electronic redox-conductivity and electrochromic properties. These compounds can be prepared by scanning of the platinum electrode potential from -0.7 to 1.7 V (vs. SCE) in acetonitrile solutions of corresponding monomers or with potentiostatic electrode polarization at -1.6 V. Optimal conditions of preparation of polymeric films based on the above complexes, the kinetics of their formation, data on stability, and parameters of electronic conductivity were presented previously. Here, the authors report the results of studies of the photosensitivity of electrodes modified with each component separately.},
doi = {},
url = {https://www.osti.gov/biblio/244013}, journal = {Russian Journal of Applied Chemistry},
number = 2,
volume = 68,
place = {United States},
year = {Thu Aug 10 00:00:00 EDT 1995},
month = {Thu Aug 10 00:00:00 EDT 1995}
}