skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Alkaline earth metal doped tin oxide as a novel oxygen storage material

Abstract

Alkaline earth metal doped tin oxide (SnO{sub 2}) hollow nanospheres with a diameter of 50 nm have been synthesized successfully via a facial solvothermal route in a very simple system composed of only ethanol, acetic acid, SnCl{sub 4}·5H{sub 2}O and A(NO{sub 3}){sub 2}·xH{sub 2}O (A = Mg, Ca, Sr, Ba). The synthesized undoped SnO{sub 2} and A-doped SnO{sub 2} hollow nanospheres were characterized by the oxygen storage capacity (OSC), X-ray diffraction, transmission electron microscopy and the Brunauer–Emmet–Teller (BET) technique. The OSC values of all samples were measured using thermogravimetric-differential thermal analysis. The incorporation of alkaline earth metal ion into tin oxide greatly enhanced the thermal stability and OSC. Especially, Ba-doped SnO{sub 2} hollow nanospheres calcined at 1000 °C for 20 h with a BET surface area of 61 m{sup 2} g{sup −1} exhibited the considerably high OSC of 457 μmol-O g{sup −1} and good thermal stability. Alkaline earth metal doped tin oxide has the potential to be a novel oxygen storage material.

Authors:
 [1]; ; ; ;  [1]; ; ;  [2];  [1]
  1. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku Sendai 980-8577 (Japan)
  2. Department of Research Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, Miyamae cho-7, Kofu 400-8511 (Japan)
Publication Date:
OSTI Identifier:
22475878
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 69; Conference: ISFM 2014: 6. international symposium on functional materials, Singapore (Singapore), 4-7 Aug 2014; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ALKALINE EARTH METALS; CAPACITY; DIFFERENTIAL THERMAL ANALYSIS; DOPED MATERIALS; NITROGEN OXIDES; OXYGEN; STABILITY; SURFACE AREA; THERMAL GRAVIMETRIC ANALYSIS; TIN CHLORIDES; TIN OXIDES; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION

Citation Formats

Dong, Qiang, Yin, Shu, Yoshida, Mizuki, Wu, Xiaoyong, Liu, Bin, Miura, Akira, Takei, Takahiro, Kumada, Nobuhiro, and Sato, Tsugio. Alkaline earth metal doped tin oxide as a novel oxygen storage material. United States: N. p., 2015. Web. doi:10.1016/J.MATERRESBULL.2014.11.018.
Dong, Qiang, Yin, Shu, Yoshida, Mizuki, Wu, Xiaoyong, Liu, Bin, Miura, Akira, Takei, Takahiro, Kumada, Nobuhiro, & Sato, Tsugio. Alkaline earth metal doped tin oxide as a novel oxygen storage material. United States. https://doi.org/10.1016/J.MATERRESBULL.2014.11.018
Dong, Qiang, Yin, Shu, Yoshida, Mizuki, Wu, Xiaoyong, Liu, Bin, Miura, Akira, Takei, Takahiro, Kumada, Nobuhiro, and Sato, Tsugio. 2015. "Alkaline earth metal doped tin oxide as a novel oxygen storage material". United States. https://doi.org/10.1016/J.MATERRESBULL.2014.11.018.
@article{osti_22475878,
title = {Alkaline earth metal doped tin oxide as a novel oxygen storage material},
author = {Dong, Qiang and Yin, Shu and Yoshida, Mizuki and Wu, Xiaoyong and Liu, Bin and Miura, Akira and Takei, Takahiro and Kumada, Nobuhiro and Sato, Tsugio},
abstractNote = {Alkaline earth metal doped tin oxide (SnO{sub 2}) hollow nanospheres with a diameter of 50 nm have been synthesized successfully via a facial solvothermal route in a very simple system composed of only ethanol, acetic acid, SnCl{sub 4}·5H{sub 2}O and A(NO{sub 3}){sub 2}·xH{sub 2}O (A = Mg, Ca, Sr, Ba). The synthesized undoped SnO{sub 2} and A-doped SnO{sub 2} hollow nanospheres were characterized by the oxygen storage capacity (OSC), X-ray diffraction, transmission electron microscopy and the Brunauer–Emmet–Teller (BET) technique. The OSC values of all samples were measured using thermogravimetric-differential thermal analysis. The incorporation of alkaline earth metal ion into tin oxide greatly enhanced the thermal stability and OSC. Especially, Ba-doped SnO{sub 2} hollow nanospheres calcined at 1000 °C for 20 h with a BET surface area of 61 m{sup 2} g{sup −1} exhibited the considerably high OSC of 457 μmol-O g{sup −1} and good thermal stability. Alkaline earth metal doped tin oxide has the potential to be a novel oxygen storage material.},
doi = {10.1016/J.MATERRESBULL.2014.11.018},
url = {https://www.osti.gov/biblio/22475878}, journal = {Materials Research Bulletin},
issn = {0025-5408},
number = ,
volume = 69,
place = {United States},
year = {Tue Sep 15 00:00:00 EDT 2015},
month = {Tue Sep 15 00:00:00 EDT 2015}
}