Growth and characterization of new semiorganic nonlinear optical and piezoelectric lithium sulfate monohydrate oxalate single crystals

Journal Article · Wed Apr 15 00:00:00 EDT 2015 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2014.12.065· OSTI ID:22475731

Yadav, Harsh ^[1]; Sinha, Nidhi ^[2]; Kumar, Binay ^[1]

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1. Crystal Lab, Department of Physics & Astrophysics, University of Delhi, Delhi 110007 (India)
2. Department of Physics & Electronics, SGTB Khalsa College, University of Delhi, Delhi 110007 (India)

Highlights: • A new semiorganic single crystal of LSO grown by slow evaporation technique. • Morphological studies of the LSO crystal deduced by BFDH law. • In the UV–vis spectrum wide transparent region and large band gap were found. • SHG is equal to KDP crystal and d{sub 33} was found to be equal to 6pC/N. • Grown crystal belongs to softer category. - Abstract: New semiorganic crystal of lithium sulfate monohydrate oxalate (LSO) for nonlinear application was synthesized by controlled slow evaporation method. The growth rate of various planes of the grown crystal was estimated by morphological study. Single crystal XRD analysis confirmed that the crystal belongs to triclinic lattice with space group P1. High transparency (∼95%) with large band gap (4.57 eV) was analyzed by UV–vis studies. FTIR and Raman spectroscopy were used to identify various functional groups present in the LSO crystal. SHG efficiency was found to be equal to the KDP crystal. Thermal stability (up to 117.54 °C) and melting point (242 °C) of the crystal were studied by TG-DTA. In dielectric measurements, the value of dielectric constant decreases with increase in frequency. Hardness studies confirmed soft nature of crystals. The piezoelectric coefficient was found to be 6pC/N along [0 0 1].

• OSTI ID: 22475731
• Journal Information: Materials Research Bulletin, Vol. 64; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
CRYSTAL GROWTH
DIFFERENTIAL THERMAL ANALYSIS
FOURIER TRANSFORMATION
HARDNESS
INFRARED SPECTRA
LITHIUM SULFATES
MELTING POINTS
MONOCRYSTALS
NONLINEAR OPTICS
OPACITY
OXALATES
PERMITTIVITY
PIEZOELECTRICITY
RAMAN SPECTROSCOPY
SPACE GROUPS
STABILITY
TRICLINIC LATTICES
X-RAY DIFFRACTION