Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands

Journal Article · Tue Dec 15 00:00:00 EST 2015 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774515070305· OSTI ID:22472053

Han, Q. -P.; Yang, X.; Li, H.; Ma, H. -X.; Yao, C. -Z.; Sun, H. ^[1]

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1. Yuncheng University, Department of Applied Chemistry (China)

3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L{sup 1}, 1) and its Mn(II) complex, [Mn(L{sup 1}){sub 2}(SCN){sub 2}]{sub ∞} (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L{sup 1} ligands, two SCN-ligands, and two oxygen atoms of other two L{sup 1} ligands to form a distorted octahedral geometry. Therefore, each L{sup 1} links Mn ions through the O and N atoms to generate 2D sheet structure.

• OSTI ID: 22472053
• Journal Information: Crystallography Reports, Vol. 60, Issue 7; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ABSORPTION SPECTROSCOPY
CRYSTAL STRUCTURE
IMIDAZOLES
INFRARED SPECTRA
LIGANDS
MANGANESE COMPLEXES
MANGANESE IONS
MONOCRYSTALS
MULTI-ELEMENT ANALYSIS
NITROGEN
ORGANIC POLYMERS
OXYGEN
SYNTHESIS
X-RAY DIFFRACTION