Synthesis and structure of a 2D → 3D framework with coexistence of hydrogen bonds and polythreading character

Journal Article · Tue Dec 15 00:00:00 EST 2015 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774515070172· OSTI ID:22472045

Zhang, Ming-Dao; Zhuang, Qi-Fan; Xu, Jing; Cao, Hui ^[1]

---

1. Nanjing University of Information Science & Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Collaborative Innovation Center for Atmospheric Environment & Equipment Technology, School of Environmental Science and Engineering (China)

The title complex, ([Co(BPPA)(5-OH-bdc)] · (H{sub 2}O)){sub n} was prepared under hydrothermal conditions based on two ligands, namely, bis(4-(pyridin-4-yl)phenyl)amine (BPPA) and 5-hydroxyisophthalic acid (5-OH-H{sub 2}bdc). 5-OH-bdc{sup 2–} anions coordinated to Co atoms to give layers in crystal. BPPA ligands coordinate to Co atoms and thread into the adjacent layers. There are hydrogen bonds between adjacent layers, giving rise to a 2D → 3D framework.

• OSTI ID: 22472045
• Journal Information: Crystallography Reports, Vol. 60, Issue 7; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
AMINES
ANIONS
ATOMS
CHEMICAL BONDS
COBALT COMPOUNDS
CRYSTALS
HYDRATES
LAYERS
LIGANDS
SYNTHESIS