Correlation of adsorption isotherms of hydrogen isotopes on mordenite adsorbents using reactive vacancy solution theory
- Faculty of Engineering and Ressource Science, Akita University, Akita-shi, Akita (Japan)
- Japan Atomic Energy Agency -JAEA, Tokai, Ibaraki (Japan)
The authors have applied the isotherm equations derived from the reactive vacancy solution theory (RVST) to correlation of experimental and highly non-ideal adsorption isotherms of hydrogen and deuterium on a mordenite adsorbent, and have examined the ability of the isotherm equations to match this correlation. Several isotherm equations such as Langmuir, Freundlich, Toth, Vacancy Solution Theory and so forth were also tested, but they did not work. For the Langmuir-Freundlich equation tests have indicated that its 'ability to correlate' of the adsorption isotherms is not satisfactory. For the multi-site Langmuir-Freundlich (MSLF) equation the correlation of the isotherms appears to be somewhat improved but remains unsatisfactory. The results show that the isotherm equations derived from RVST can better correlate the experimental isotherms.
- OSTI ID:
- 22429750
- Journal Information:
- Fusion Science and Technology, Vol. 67, Issue 3; Conference: TRITIUM 2013: 10. International Conference on Tritium Science and Technology, Nice Acropolis (France), 21-25 Oct 2013; Other Information: Country of input: France; 4 refs.; ISSN 1536-1055
- Country of Publication:
- United States
- Language:
- English
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