Comparison of topotactic fluorination methods for complex oxide films
- Centralized Research Facilities, Drexel University, Philadelphia, Pennsylvania 19104 (United States)
We have investigated the synthesis of SrFeO{sub 3−α}F{sub γ} (α and γ ≤ 1) perovskite films using topotactic fluorination reactions utilizing poly(vinylidene fluoride) as a fluorine source. Two different fluorination methods, a spin-coating and a vapor transport approach, were performed on as-grown SrFeO{sub 2.5} films. We highlight differences in the structural, compositional, and optical properties of the oxyfluoride films obtained via the two methods, providing insight into how fluorination reactions can be used to modify electronic and optical behavior in complex oxide heterostructures.
- OSTI ID:
- 22415299
- Journal Information:
- APL materials, Vol. 3, Issue 6; Other Information: (c) 2015 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 2166-532X
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and characterization of the La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} system and the fluorinated phases La{sub 1-x}Sr{sub x}FeO{sub 3-x}F{sub x}
Structural evolution of epitaxial SrCoO x films near topotactic phase transition
Structural evolution of epitaxial SrCoO{sub x} films near topotactic phase transition
Journal Article
·
Tue Nov 15 00:00:00 EST 2011
· Journal of Solid State Chemistry
·
OSTI ID:22415299
Structural evolution of epitaxial SrCoO x films near topotactic phase transition
Journal Article
·
Tue Dec 01 00:00:00 EST 2015
· AIP Advances
·
OSTI ID:22415299
Structural evolution of epitaxial SrCoO{sub x} films near topotactic phase transition
Journal Article
·
Tue Dec 15 00:00:00 EST 2015
· AIP Advances
·
OSTI ID:22415299