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Title: Radiation liquid-phase graft polymerization of acrylic acid to polyethylene films in the presence of hydroquinone

Journal Article · · High Energy Chemistry
OSTI ID:224078

Graft polymerization of acrylic acid to polyethylene films from 15-70% toluene solutions initiated by {sup 60}Co {gamma}-rays was investigated for fabrication of ion-exchange membranes with good deformation-strength properties. It was found that without hydroquinone, the yield of graft polyacrylic acid was a weak function of the absorbed dose, and homopolymerization of the monomer took place intensely. The degree of conversion of acrylic acid decreased, and the degree of grafting increased in the presence of hydroquinone. The equilibrium distribution of the graft polyacrylic acid over the cross section of the films caused their elasticity. 15 refs., 1 fig., 4 tabs.

OSTI ID:
224078
Journal Information:
High Energy Chemistry, Vol. 25, Issue 5; Other Information: PBD: Mar 1992; TN: Translated from Khimiya Vysokikh Energii; 25: No. 5, 433-437(Sep-Oct 1991)
Country of Publication:
United States
Language:
English