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Title: Local formation of nitrogen-vacancy centers in diamond by swift heavy ions

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4903075· OSTI ID:22402731
 [1]; ;  [2]; ; ;  [3];  [3];  [4]
  1. Accelerator Technology and Applied Physics Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)
  2. The Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)
  3. GSI Helmholtz Center for Heavy Ion research, 64291 Darmstadt (Germany)
  4. Ilmenau University of Technology, Department of Microelectronics and Nanoelectric Systems, 98684 Ilmenau (Germany)

We exposed nitrogen-implanted diamonds to beams of swift heavy ions (∼1 GeV, ∼4 MeV/u) and find that these irradiations lead directly to the formation of nitrogen vacancy (NV) centers, without thermal annealing. We compare the photoluminescence intensities of swift heavy ion activated NV{sup −} centers to those formed by irradiation with low-energy electrons and by thermal annealing. NV{sup −} yields from irradiations with swift heavy ions are 0.1 of yields from low energy electrons and 0.02 of yields from thermal annealing. We discuss possible mechanisms of NV center formation by swift heavy ions such as electronic excitations and thermal spikes. While forming NV centers with low efficiency, swift heavy ions could enable the formation of three dimensional NV{sup −} assemblies over relatively large distances of tens of micrometers. Further, our results show that NV center formation is a local probe of (partial) lattice damage relaxation induced by electronic excitations from swift heavy ions in diamond.

OSTI ID:
22402731
Journal Information:
Journal of Applied Physics, Vol. 116, Issue 21; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English

Cited By (7)

Irradiation of materials with short, intense ion pulses at NDCX-II journal May 2017
Spin properties of NV centers in high-pressure, high-temperature grown diamond journal November 2018
Quantum nanophotonics in diamond [Invited] journal January 2016
Spin properties of NV centers in high-pressure, high-temperature grown diamond text January 2018
Review Article: Quantum Nanophotonics in Diamond preprint January 2016
Photothermal effects during nanodiamond synthesis from a carbon aerogel in a laser-heated diamond anvil cell preprint January 2017
Direct formation of nitrogen-vacancy centers in nitrogen doped diamond along the trajectories of swift heavy ions text January 2020