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Title: Graphite edge controlled registration of monolayer MoS{sub 2} crystal orientation

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4919923· OSTI ID:22398997
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  1. Department of Physics, National Taiwan University, Taipei 10617, Taiwan (China)
  2. Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China)

Transition metal dichalcogenides such as the semiconductor MoS{sub 2} are a class of two-dimensional crystals. The surface morphology and quality of MoS{sub 2} grown by chemical vapor deposition are examined using atomic force and scanning tunneling microscopy techniques. By analyzing the moiré patterns from several triangular MoS{sub 2} islands, we find that there exist at least five different superstructures and that the relative rotational angles between the MoS{sub 2} adlayer and graphite substrate lattices are typically less than 3°. We conclude that since MoS{sub 2} grows at graphite step-edges, it is the edge structure which controls the orientation of the islands, with those growing from zig-zag (or armchair) edges tending to orient with one lattice vector parallel (perpendicular) to the step-edge.

OSTI ID:
22398997
Journal Information:
Applied Physics Letters, Vol. 106, Issue 18; Other Information: (c) 2015 Author(s); Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English