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Title: Measuring charge carrier mobility in photovoltaic devices with micron-scale resolution

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4915614· OSTI ID:22395777
 [1]
  1. Sustainable Energy Technologies Department, Brookhaven National Laboratory, Upton, New York 11973 (United States)

We present a charge-extraction technique, micron-scale charge extraction by linearly increasing voltage, which enables simultaneous spatially resolved measurements of charge carrier mobility and photocurrent in thin-film photovoltaic devices with micron-scale resolution. An intensity-modulated laser with beam diameter near the optical diffraction limit is scanned over the device, while a linear voltage ramp in reverse bias is applied at each position of illumination. We calculate the majority carrier mobility, photocurrent, and number of photogenerated charge carriers from the resulting current transient. We demonstrate this technique on an organic photovoltaic device, but it is applicable to a wide range of photovoltaic materials.

OSTI ID:
22395777
Journal Information:
Applied Physics Letters, Vol. 106, Issue 11; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English