Preparation and supercapacitor application of the single crystal nickel hydroxide and oxide nanosheets

Journal Article · Sun Sep 01 00:00:00 EDT 2013 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2013.05.049· OSTI ID:22341793

Li, Qing ^[1]; Ni, Haifang ^[2]; Cai, Yun; Cai, Xiaoyan ^[1]; Liu, Yongjun ^[3]; Chen, Gang ^[1]; Fan, Li-Zhen ^[2]; Wang, Yude ^[1]

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1. Department of Materials Science and Engineering, Yunnan University, 650091 Kunming (China)
2. Institute of Materials Science and Engineering, University of Science and Technology Beijing, 100083 Beijing (China)
3. Advanced Analysis and Measurement Center, Yunnan University, 650091 Kunming (China)

Graphical abstract: The nickel hydroxide and nickel oxide nanosheets prepared using CTAB at room temperature exhibit a high specific capacitance, prompt charge/discharge rate. - Highlights: • The nickel hydroxide nanosheets were prepared using CTAB at room temperature. • Ni(OH){sub 2} nanosheet can be successfully converted to NiO nanosheet via calcination. • The NiO nanosheet has a specific capacitance of 388 F g{sup −1} at 5 A g{sup −1} in KOH solution. • Anneal temperature impacts capacitive properties as electrode. - Abstract: The single crystalline Ni(OH){sub 2} nanosheets were synthesized by a simple chemical precipitation method using nickel chloride as precursors and ammonia as precipitating agent. The Ni(OH){sub 2} nanosheets were successfully converted to NiO nanosheets via calcination under appropriate conditions. Analytical methods such as X-ray diffraction (XRD) spectra, scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and Fourier transformed infrared (FTIR) spectra were employed to characterize the morphology and microstructure of the final products. The experimental results revealed that Ni(OH){sub 2} nanosheets were shape-preserved transformed to NiO nanosheets at 250 °C for 24 h. Ni(OH){sub 2} and NiO nanosheets were directly functionalized as supercapacitor electrodes for potential energy storage applications, whose charge–discharge properties, electrochemical impedance spectra, cyclic voltammetry, and cycle performance were examined. The experimental results show that the single-crystalline NiO nanosheets are a promising candidate for the supercapacitor electrode. They exhibit a high specific capacitance, prompt charge/discharge rate.

• OSTI ID: 22341793
• Journal Information: Materials Research Bulletin, Vol. 48, Issue 9; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
77 NANOSCIENCE AND NANOTECHNOLOGY
AMMONIA
FOURIER TRANSFORMATION
INFRARED SPECTRA
MICROSTRUCTURE
MONOCRYSTALS
NANOSTRUCTURES
NICKEL HYDROXIDES
NICKEL OXIDES
PRECIPITATION
SCANNING ELECTRON MICROSCOPY
SYNTHESIS
TRANSMISSION ELECTRON MICROSCOPY
VOLTAMETRY
X-RAY DIFFRACTION