Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2}
Abstract
Graphical abstract: - Highlights: • Semiorganic NLO material NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} has been grown with sizes up to 8 × 5 × 2 mm{sup 3}. • It crystallizes in the noncentrosymmetric Monoclinic space group P2. • Thermal analysis demonstrated NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} are thermally stable up to 280. • NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} has an absorption edge about 220 nm in the UV region. • It exhibits a NLO efficiency of about two times that of KDP (KH{sub 2}PO{sub 4}) standard. - Abstract: Single crystal of the semiorganic NLO material NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} has been grown with sizes up to 8 × 5 × 2 mm{sup 3} by the slow evaporation method. The crystal structure of this compound was determined by single crystal X-ray diffraction. It crystallizes in the Monoclinic space group P2 with lattice parameters a = 5.4045(11) Å, b = 11.692(2) Å, c = 9.4773(19) Å and Z = 2. Thermal analysis demonstrated NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} are thermally stable up to 280 °C. NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} exhibits an absorption edge about 220 nm in the UV region. The powder second-harmonic generation (SHG) measurement performed on the groundmore »
- Authors:
-
- National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China)
- Center for Crystal Research and Development, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)
- Publication Date:
- OSTI Identifier:
- 22341750
- Resource Type:
- Journal Article
- Journal Name:
- Materials Research Bulletin
- Additional Journal Information:
- Journal Volume: 48; Journal Issue: 9; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; ABSORPTION; CRYSTAL GROWTH; EFFICIENCY; EVAPORATION; HARMONIC GENERATION; LATTICE PARAMETERS; MONOCLINIC LATTICES; MONOCRYSTALS; OPTICAL PROPERTIES; POTASSIUM PHOSPHATES; SPACE GROUPS; THERMAL ANALYSIS; X-RAY DIFFRACTION
Citation Formats
Huang, Hongwei, Yao, Wenjiao, He, Ying, Tian, Na, Chen, Chuangtian, and Zhang, Yihe. Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2}. United States: N. p., 2013.
Web. doi:10.1016/J.MATERRESBULL.2013.04.062.
Huang, Hongwei, Yao, Wenjiao, He, Ying, Tian, Na, Chen, Chuangtian, & Zhang, Yihe. Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2}. United States. https://doi.org/10.1016/J.MATERRESBULL.2013.04.062
Huang, Hongwei, Yao, Wenjiao, He, Ying, Tian, Na, Chen, Chuangtian, and Zhang, Yihe. 2013.
"Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2}". United States. https://doi.org/10.1016/J.MATERRESBULL.2013.04.062.
@article{osti_22341750,
title = {Semiorganic nonlinear optical material: Crystal growth, structure and optical properties of NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2}},
author = {Huang, Hongwei and Yao, Wenjiao and He, Ying and Tian, Na and Chen, Chuangtian and Zhang, Yihe},
abstractNote = {Graphical abstract: - Highlights: • Semiorganic NLO material NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} has been grown with sizes up to 8 × 5 × 2 mm{sup 3}. • It crystallizes in the noncentrosymmetric Monoclinic space group P2. • Thermal analysis demonstrated NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} are thermally stable up to 280. • NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} has an absorption edge about 220 nm in the UV region. • It exhibits a NLO efficiency of about two times that of KDP (KH{sub 2}PO{sub 4}) standard. - Abstract: Single crystal of the semiorganic NLO material NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} has been grown with sizes up to 8 × 5 × 2 mm{sup 3} by the slow evaporation method. The crystal structure of this compound was determined by single crystal X-ray diffraction. It crystallizes in the Monoclinic space group P2 with lattice parameters a = 5.4045(11) Å, b = 11.692(2) Å, c = 9.4773(19) Å and Z = 2. Thermal analysis demonstrated NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} are thermally stable up to 280 °C. NaB(L-C{sub 4}H{sub 4}O{sub 5}){sub 2} exhibits an absorption edge about 220 nm in the UV region. The powder second-harmonic generation (SHG) measurement performed on the ground crystal indicates that it has a NLO efficiency of about 2 times that of KDP (KH{sub 2}PO{sub 4}) standard. In addition, the origin of stronger SHG effect was discussed.},
doi = {10.1016/J.MATERRESBULL.2013.04.062},
url = {https://www.osti.gov/biblio/22341750},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = 9,
volume = 48,
place = {United States},
year = {Sun Sep 01 00:00:00 EDT 2013},
month = {Sun Sep 01 00:00:00 EDT 2013}
}