Monovalent metal phenylphosphonates and phenylarsonates: Single crystal X-ray structures of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = K, Rb, Cs, Tl) and Na(HO{sub 3}AsPh)(H{sub 2}O{sub 3}AsPh) and methylamine intercalation of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K, Tl)
Single crystal X-ray structures of known A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = K, Rb, Cs, Tl) phenylphosphonates and sodium phenylarsonate, Na(HO{sub 3}AsPh)(H{sub 2}O{sub 3}AsPh) have been determined. This and previous studies together describe the four types of structures of a series of seven A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K, Rb, Cs, Tl, NH{sub 4}) phenylphosphonates. Sodium phenylarsonate is isostructural with its phenylphosphonate analogue. A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K and Tl) compounds undergo methylamine intercalation. - Graphical abstract: Amongst A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = alkali metal, Tl) phenylphosphonates of four structure types, lithium, sodium, potassium and thallium compounds undergo methylamine intercalation. - Highlights: • X-ray structures of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = K, Rb, Cs, Tl) and Na(HO{sub 3}AsPh)(H{sub 2}O{sub 3}AsPh). • Four structure types of seven A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = monovalent ion) compounds. • Methylamine intercalation of A(HO{sub 3}PPh)(H{sub 2}O{sub 3}PPh) (A = Li, Na, K, Tl) compounds.
- OSTI ID:
- 22309053
- Journal Information:
- Journal of Solid State Chemistry, Vol. 203; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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