Synthesis and characterization of Ni(II) complex with 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-dienium bromide
Journal Article
·
· AIP Conference Proceedings
- School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)
Nickel(II) complex have been synthesized by treating a 14-membered ring tetraaza macrocyclic compound, 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-dienium, bromide (Me{sub 6}N{sub 4}H{sub 4})Br{sub 2} with nickel acetate in metanol. The complex was characterized using elemental analysis, Fourier Transform Infrared (FTIR), Ultraviolet-Visible (UV-Vis), and single crystal diffraction (X-ray). The nickel atom coordinates through four nitrogen atoms in the ligand. Square planar geometry has been proposed for this complex.
- OSTI ID:
- 22308329
- Journal Information:
- AIP Conference Proceedings, Vol. 1614, Issue 1; Conference: 2014 UKM FST postgraduate colloquium, Selangor (Malaysia), 9-11 Apr 2014; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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· AIP Conference Proceedings
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OSTI ID:22308329
Synthesis and properties of nickel(I) and Nickel(II) complexes of a series of macrocyclic N{sub 4} ligands: Crystal structures of C-RSSR-[Ni{sup I}HTIM](ClO{sub 4}), C-RSSR-[Ni{sup II}HTIM](ClO{sub 4}){sub 2}, C-RRSS-[Ni{sup II}HTIM](ClO{sub 4}){sub 2}, and [Ni{sup II}TIM](ClO{sub 4}){sub 2} (HTIM = 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradecane, TIM = 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene)
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Wed Dec 07 00:00:00 EST 1994
· Inorganic Chemistry
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OSTI ID:22308329
Complexation of 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7,14-diene dithiocyanate with nickel (II) acetate
Journal Article
·
Wed Nov 27 00:00:00 EST 2013
· AIP Conference Proceedings
·
OSTI ID:22308329