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Title: Cyclododecane as support material for clean and facile transfer of large-area few-layer graphene

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4895733· OSTI ID:22303530
; ; ; ;  [1];  [2]; ;  [3]; ; ;  [4]
  1. ENEA, Materials Technology Unit, Surface Technology Laboratory, Casaccia Research Centre, Via Anguillarese 301, 00060 Rome (Italy)
  2. ENEA, Technical Unit for Renewable Energies Sources, Casaccia Research Center, Via Anguillarese 301, 00060 Rome (Italy)
  3. ENEA, Portici Research Centre, P.le E. Fermi 1, 80055 Portici (Italy)
  4. Research Center on Nanotechnology Applied to Engineering of Sapienza (CNIS), SSNLab, Sapienza University of Rome, P.le Aldo Moro 5, 00185 Rome (Italy)

The transfer of chemical vapor deposited graphene is a crucial process, which can affect the quality of the transferred films and compromise their application in devices. Finding a robust and intrinsically clean material capable of easing the transfer of graphene without interfering with its properties remains a challenge. We here propose the use of an organic compound, cyclododecane, as a transfer material. This material can be easily spin coated on graphene and assist the transfer, leaving no residues and requiring no further removal processes. The effectiveness of this transfer method for few-layer graphene on a large area was evaluated and confirmed by microscopy, Raman spectroscopy, x-ray photoemission spectroscopy, and four-point probe measurements. Schottky-barrier solar cells with few-layer graphene were fabricated on silicon wafers by using the cyclododecane transfer method and outperformed reference cells made by standard methods.

OSTI ID:
22303530
Journal Information:
Applied Physics Letters, Vol. 105, Issue 11; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English