Structural and magnetic properties of the ordered FePt{sub 3}, FePt and Fe{sub 3}Pt nanoparticles
- Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China)
- Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)
The Fe{sub x}Pt{sub 100−x} nanoparticles (NPs) with different nominal atomic rations (30≤x≤80) were synthesized at 700 °C by the sol–gel method. The structure, morphology and magnetic properties of the samples were investigated. When the Fe content in the Fe–Pt alloy NPs was 30 at%, FePt{sub 3} NPs were successfully synthesized. With the increase in Fe content up to 50 at%, it was found that the superlattice reflections (0 0 1) and (1 1 0) appeared, which indicated the formation of the L1{sub 0}-FePt phase. Meanwhile, the FePt{sub 3} fraction was reduced. When the Fe content increased to 60 at%, single-phase L1{sub 0}-FePt NPs were synthesized. The coercivity (Hc), saturation magnetization (Ms) and chemical order parameter S for Fe{sub 60}Pt{sub 40} NPs were as high as 10,200 Oe, 17.567 emu/g and 0.928, respectively. With the further increase of the Fe content to 80 at%, only Fe{sub 3}Pt phase existed and the Hc of the Fe{sub 3}Pt NPs decreased drastically to 360 Oe. - Graphical abstract: Fe{sub 3}Pt, FePt and FePt{sub 3} nanoparticles was obtained by sol–gel method. The effect of iron and platinum content on structural and magnetic properties of the FePt nanoparticles was investigated. Display Omitted - Highlights: • L1{sub 2}-FePt{sub 3}, L1{sub 0}-FePt and L1{sub 2}-Fe{sub 3}Pt NPs were synthesized by sol–gel method. • The chemical order parameter S affects the magnetic properties of the Fe–Pt alloy. • Structural and magnetic properties of the Fe–Pt alloy NPs were studied. • The synthetic route in this study will open up the possibilities of practical use.
- OSTI ID:
- 22274177
- Journal Information:
- Journal of Solid State Chemistry, Vol. 209; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
Similar Records
Enhanced magnetic behaviors of CoPt nanoparticles by addition of SiO{sub 2}
Rapid ordering of Zr-doped FePt alloy films