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Title: The physics and chemistry of the Schottky barrier height

Journal Article · · Applied Physics Reviews
DOI:https://doi.org/10.1063/1.4858400· OSTI ID:22269572
 [1]
  1. Department of Physics, Brooklyn College, CUNY, 2900 Bedford Avenue, Brooklyn, New York 11210, USA and Physics Ph.D. Program, The Graduate Center, CUNY, 365 Fifth Avenue, New York 10016 (United States)

The formation of the Schottky barrier height (SBH) is a complex problem because of the dependence of the SBH on the atomic structure of the metal-semiconductor (MS) interface. Existing models of the SBH are too simple to realistically treat the chemistry exhibited at MS interfaces. This article points out, through examination of available experimental and theoretical results, that a comprehensive, quantum-mechanics-based picture of SBH formation can already be constructed, although no simple equations can emerge, which are applicable for all MS interfaces. Important concepts and principles in physics and chemistry that govern the formation of the SBH are described in detail, from which the experimental and theoretical results for individual MS interfaces can be understood. Strategies used and results obtained from recent investigations to systematically modify the SBH are also examined from the perspective of the physical and chemical principles of the MS interface.

OSTI ID:
22269572
Journal Information:
Applied Physics Reviews, Vol. 1, Issue 1; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 1931-9401
Country of Publication:
United States
Language:
English