Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic

Journal Article · Wed Nov 27 00:00:00 EST 2013 · AIP Conference Proceedings

DOI:https://doi.org/10.1063/1.4858762· OSTI ID:22262654

Bt Safiin, Nurul Atikah; Yarmo, Ambar; Yamin, Bohari M. ^[1]

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1. School of Chemical Science and Food Technology. Faculty Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan (Malaysia)

A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70°C followed by a gradual mass loss until the whole structure collapsed at about 400°C.

• OSTI ID: 22262654
• Journal Information: AIP Conference Proceedings, Vol. 1571, Issue 1; Conference: 2013 UKM FST postgraduate colloquium, Selangor (Malaysia), 3-4 Jul 2013; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ABSORPTION SPECTROSCOPY
BROMIDES
CERIUM
INFRARED SPECTRA
MIXTURES
ORGANOMETALLIC COMPOUNDS
SULFATES
SYNTHESIS
THERMAL GRAVIMETRIC ANALYSIS
X RADIATION