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Title: Resistive switching of a TaO{sub x}/TaON double layer via ionic control of carrier tunneling

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4871692· OSTI ID:22262589
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  1. Department of Nano-Scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)
  2. Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)
  3. Department of Materials Science and Engineering and Department of Energy Systems Research, Ajou University, Suwon 443-739 (Korea, Republic of)

Resistance random access memory (RRAM) is an attractive candidate for future non-volatile memory due to its superior features. As the oxide thickness is scaled down, the charge transport mechanism is also subject to the transition from hopping to tunneling dominant process, which is critically related to the interfacial electronic band structure. A TaO{sub x}/TaON double layer-based RRAM is fabricated and characterized in this work. Upon TaON insertion at the lower interface, the improved switching behavior is observed. The TaON at the bottom electrode interface blocks oxygen vacancy percolation due to strong N-O bonds and also modifies interfacial band alignment to lower the injected electron energy from bottom electrode due to higher tunneling barrier height than that of TaO{sub x}/Pt. This study suggested that a defect-minimized insertion layer like TaON with a proper interfacial band alignment is pivotal in RRAM for the effective ionic control of carrier tunneling resulting in non-linear I-V behavior with improved properties.

OSTI ID:
22262589
Journal Information:
Applied Physics Letters, Vol. 104, Issue 15; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English