Effect of ZrO{sub 2}-doping of nanosized Fe{sub 2}O{sub 3}/MgO system on its structural, surface and catalytic properties
- National Research Center, Dokki, Cairo (Egypt)
Highlights: ► Preparation and characterization nano-sized ZrO{sub 2}-doped Fe{sub 2}O{sub 3}/MgO system. ► Pure and doped solids calcined at 500 and 700 °C are mesoporous adsorbents. ► ZrO{sub 2}-doping increased the lattice constant “a” of MgO lattice to an extent proportional to the amount of ZrO{sub 2} added. ► The catalytic activity in H{sub 2}O{sub 2} decomposition was found to increase as a function of dopant concentration. -- Abstract: Fe{sub 2}O{sub 3}/MgO system was prepared by wet impregnation method followed by treatment with different amounts of Zr-dopant salt then heating at 500 and 700 °C. The dopant concentrations were 0.48, 0.95 and 1.4 mol% ZrO{sub 2}. Pure and variously doped solids were characterized using XRD, N{sub 2}-adsorption isotherms carried out at −196 °C and catalytic decomposition of H{sub 2}O{sub 2} in aqueous solution at 25–35 °C. The results revealed that the nanosized MgO phase was only detected in the diffractograms of pure and doped solids calcined at 500 °C. Heating pure and doped solids at 700 °C produced nanosized MgFe{sub 2}O{sub 4} phase together with MgO phase. Pure and ZrO{sub 2}-doped solids calcined at 500 and 700 °C are mesoporous adsorbents. The doping process brought about a measurable decrease in the S{sub BET} of Fe{sub 2}O{sub 3}/MgO system with subsequent increase in its catalytic activity. The catalytic activity of the investigated system toward H{sub 2}O{sub 2} decomposition, expressed as reaction rate constant per unit surface area was found to increase as a function of dopant concentration. The maximum increase in the reaction rate constant per unit surface area measured for the reaction carried out at 30 °C attained 125% for the heavily doped samples. This significant increase was based on the catalytic activity of pure catalyst sample measured under the same conditions.
- OSTI ID:
- 22215757
- Journal Information:
- Materials Research Bulletin, Vol. 47, Issue 9; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
77 NANOSCIENCE AND NANOTECHNOLOGY
ADSORBENTS
ADSORPTION ISOTHERMS
AQUEOUS SOLUTIONS
DECOMPOSITION
DOPED MATERIALS
FERRITES
HYDROGEN PEROXIDE
IRON OXIDES
LATTICE PARAMETERS
MAGNESIUM OXIDES
NANOSTRUCTURES
REACTION KINETICS
SOLIDS
SURFACE AREA
SURFACES
X-RAY DIFFRACTION
ZIRCONIUM OXIDES