Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate

Vijayakumar, P.; Ramasamy, P.

doi:10.1016/J.MATERRESBULL.2012.01.011

Title: Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate

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Abstract

Graphical abstract: p-Toluidinium p-toluenesulphonate (p-TTS) an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that p-TTS crystallizes in monoclinic crystal system. p-TTS single crystal belongs to negative birefringence crystal. Second harmonic conversion efficiency of p-TTS has been found to be 1.3 times higher than that of KDP. Multiple shot surface laser damage threshold is determined to be 0.30 GW/cm{sup 2} at 1064 nm laser radiation. Highlights: Black-Right-Pointing-Pointer It deals with the synthesis, growth and characterization of p-TTS an organic NLO crystal. Black-Right-Pointing-Pointer Wide optical transparency window between 280 nm and 1100 nm. Black-Right-Pointing-Pointer Negative birefringence crystal and dispersion of birefringence is negligibly small. Black-Right-Pointing-Pointer Thermal study reveals that the grown crystal is stable up to 210 Degree-Sign C. Black-Right-Pointing-Pointer Multiple shot surface laser damage threshold is 0.30 GW/cm{sup 2} at 1064 nm laser radiation. -- Abstract: p-Toluidinium p-toluenesulphonate (p-TTS) an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that p-TTS crystallizes in monoclinic crystal system. The structural perfection of the grown p-TTS single crystal has been analyzed by high-resolution X-raymore »« less

Authors:

Vijayakumar, P. ^[1]; Ramasamy, P. ^[1]

Centre for Crystal Growth, SSN College of Engineering, SSN Nagar, Tamilnadu 603110 (India)

Publication Date:: Sun Apr 15 00:00:00 EDT 2012

OSTI Identifier:: 22212488

Resource Type:: Journal Article

Journal Name:: Materials Research Bulletin

Additional Journal Information:: Journal Volume: 47; Journal Issue: 4; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; AQUEOUS SOLUTIONS; BIREFRINGENCE; CRYSTAL GROWTH; DIELECTRIC MATERIALS; EFFICIENCY; EVAPORATION; FOURIER TRANSFORMATION; LASER RADIATION; MONOCRYSTALS; NEODYMIUM LASERS; ORGANIC COMPOUNDS; PERMITTIVITY; SURFACES; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; THERMODYNAMIC PROPERTIES; X-RAY DIFFRACTION

Citation Formats


                    Vijayakumar, P., Anandha Babu, G., E-mail: anandcgc@gmail.com, and Ramasamy, P. Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate.  United States: N. p., 2012. 
        Web.  doi:10.1016/J.MATERRESBULL.2012.01.011.

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                    Vijayakumar, P., Anandha Babu, G., E-mail: anandcgc@gmail.com, & Ramasamy, P. Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate.  United States.  https://doi.org/10.1016/J.MATERRESBULL.2012.01.011

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                    Vijayakumar, P., Anandha Babu, G., E-mail: anandcgc@gmail.com, and Ramasamy, P. 2012.  
        "Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate".  United States.  https://doi.org/10.1016/J.MATERRESBULL.2012.01.011.

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@article{osti_22212488,

  title        = {Synthesis, crystal growth and characterization of nonlinear optical organic crystal: p-Toluidinium p-toluenesulphonate},

  author       = {Vijayakumar, P. and Anandha Babu, G., E-mail: anandcgc@gmail.com and Ramasamy, P.},

  abstractNote = {Graphical abstract: p-Toluidinium p-toluenesulphonate (p-TTS) an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that p-TTS crystallizes in monoclinic crystal system. p-TTS single crystal belongs to negative birefringence crystal. Second harmonic conversion efficiency of p-TTS has been found to be 1.3 times higher than that of KDP. Multiple shot surface laser damage threshold is determined to be 0.30 GW/cm{sup 2} at 1064 nm laser radiation. Highlights: Black-Right-Pointing-Pointer It deals with the synthesis, growth and characterization of p-TTS an organic NLO crystal. Black-Right-Pointing-Pointer Wide optical transparency window between 280 nm and 1100 nm. Black-Right-Pointing-Pointer Negative birefringence crystal and dispersion of birefringence is negligibly small. Black-Right-Pointing-Pointer Thermal study reveals that the grown crystal is stable up to 210 Degree-Sign C. Black-Right-Pointing-Pointer Multiple shot surface laser damage threshold is 0.30 GW/cm{sup 2} at 1064 nm laser radiation. -- Abstract: p-Toluidinium p-toluenesulphonate (p-TTS) an organic nonlinear optical crystal has been grown from the aqueous solution by slow evaporation solution growth technique. Single crystal X-ray diffraction analysis reveals that p-TTS crystallizes in monoclinic crystal system. The structural perfection of the grown p-TTS single crystal has been analyzed by high-resolution X-ray diffraction rocking curve measurements. Fourier transform infrared spectral studies have been performed to identify the functional groups. The optical transmittance window and the lower cutoff wavelength of the grown crystals have been identified by UV-vis-IR studies. Birefringence of p-TTS crystal has been studied using channel spectrum measurement. The laser damage threshold value was measured using Nd:YAG laser. The second harmonic conversion efficiency of p-TTS has been determined using Kurtz powder technique. Thermo gravimetric and differential thermal analyses were used to study its thermal properties. Dielectric constant, dielectric loss and AC conductivity of the grown p-TTS single crystal has been studied.},

  doi          = {10.1016/J.MATERRESBULL.2012.01.011},

  url          = {https://www.osti.gov/biblio/22212488},
  journal      = {Materials Research Bulletin},

  issn         = {0025-5408},

  number       = 4,

  volume       = 47,

  place        = {United States},

  year         = {Sun Apr 15 00:00:00 EDT 2012},

  month        = {Sun Apr 15 00:00:00 EDT 2012}

}

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