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Title: CuO-CeO{sub 2} binary oxide nanoplates: Synthesis, characterization, and catalytic performance for benzene oxidation

Journal Article · · Materials Research Bulletin
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  1. State Key Laboratory of Multiphase Complex System, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 (China)

This work reports the first synthesis of CuO-CeO{sub 2} binary oxides with a plate-like morphology by a solvothermal method. The as-prepared CuO-CeO{sub 2} nanoplates calcined at 400 {sup o}C were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectrum, and tested for catalytic oxidation of dilute benzene in air. Various structural characterizations showed that large amounts of copper species were exposed on the CuO-CeO{sub 2} nanoplate surface. The effect of the synthesis conditions on the structure of the product, as well as the growth process of the nanoplates, has been studied and discussed. The CuO-CeO{sub 2} nanoplates exhibited an excellent catalytic activity for benzene oxidation despite its relatively low surface area and could catalyze the complete oxidation of benzene at a temperature as low as 240 {sup o}C.

OSTI ID:
22202513
Journal Information:
Materials Research Bulletin, Vol. 44, Issue 12; Other Information: Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English