Structure of substituted 2-(phenoxy)benzimidazoles
Abstract
The synthesis and X-ray diffraction study of 1-benzyl-2-[2-(5-ethyltetrazole-2-yl)-phenoxy]-1H-benzimidazole and 1-benzyl-2-[2-(5-ethyltetrazole-2-yl)-4-nitrophenoxy]-1H-benzimidazole single crystals have been performed. The oxidative splitting of an azo-hydrazone group of 1-(2-hydroxy-(5-nitro)phenyl)-3-ethyl-5-(benzylbenzimidazolyl)formazans, a break in the C2-N1 bond, the interaction of o-hydroxyl group of aryl fragment with oxygen, and the formation of new 2-(phenoxy)benzimidazoles are found to occur in the presence of perchlorate iron(III).
- Authors:
-
- Ural State Forestry University (Russian Federation)
- Russian Academy of Sciences, Institute of Organic Synthesis, Ural Branch (Russian Federation)
- Publication Date:
- OSTI Identifier:
- 22156322
- Resource Type:
- Journal Article
- Journal Name:
- Crystallography Reports
- Additional Journal Information:
- Journal Volume: 58; Journal Issue: 2; Other Information: Copyright (c) 2013 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; BENZIMIDAZOLES; HYDRAZONES; HYDROXIDES; INTERACTIONS; IRON; OXIDATION; OXYGEN; PERCHLORATES; SYNTHESIS; X-RAY DIFFRACTION
Citation Formats
Pavlova, I. S., E-mail: biosphera@usfeu.ru, Pervova, I. G., Lipunova, G. N., Novikova, R. K., Slepukhin, P. A., and Lipunov, I. N. Structure of substituted 2-(phenoxy)benzimidazoles. United States: N. p., 2013.
Web. doi:10.1134/S106377451302020X.
Pavlova, I. S., E-mail: biosphera@usfeu.ru, Pervova, I. G., Lipunova, G. N., Novikova, R. K., Slepukhin, P. A., & Lipunov, I. N. Structure of substituted 2-(phenoxy)benzimidazoles. United States. https://doi.org/10.1134/S106377451302020X
Pavlova, I. S., E-mail: biosphera@usfeu.ru, Pervova, I. G., Lipunova, G. N., Novikova, R. K., Slepukhin, P. A., and Lipunov, I. N. 2013.
"Structure of substituted 2-(phenoxy)benzimidazoles". United States. https://doi.org/10.1134/S106377451302020X.
@article{osti_22156322,
title = {Structure of substituted 2-(phenoxy)benzimidazoles},
author = {Pavlova, I. S., E-mail: biosphera@usfeu.ru and Pervova, I. G. and Lipunova, G. N. and Novikova, R. K. and Slepukhin, P. A. and Lipunov, I. N.},
abstractNote = {The synthesis and X-ray diffraction study of 1-benzyl-2-[2-(5-ethyltetrazole-2-yl)-phenoxy]-1H-benzimidazole and 1-benzyl-2-[2-(5-ethyltetrazole-2-yl)-4-nitrophenoxy]-1H-benzimidazole single crystals have been performed. The oxidative splitting of an azo-hydrazone group of 1-(2-hydroxy-(5-nitro)phenyl)-3-ethyl-5-(benzylbenzimidazolyl)formazans, a break in the C2-N1 bond, the interaction of o-hydroxyl group of aryl fragment with oxygen, and the formation of new 2-(phenoxy)benzimidazoles are found to occur in the presence of perchlorate iron(III).},
doi = {10.1134/S106377451302020X},
url = {https://www.osti.gov/biblio/22156322},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 2,
volume = 58,
place = {United States},
year = {Fri Mar 15 00:00:00 EDT 2013},
month = {Fri Mar 15 00:00:00 EDT 2013}
}
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