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Title: Determination of the melting threshold of TiO{sub 2} thin films processed by excimer laser irradiation

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4728159· OSTI ID:22089241
 [1];  [2];  [1]
  1. Chimie des Interactions Plasma-Surface, Universite de Mons, 23, Place du Parc, 7000 Mons (Belgium)
  2. Service de Physique Theorique et Mathematique, Universite de Mons, 6 Avenue du champ de Mars, 7000 Mons (Belgium)

Processing surfaces by laser needs an understanding of the mechanisms generated by irradiation. In this work, to gain understanding of the mechanisms occurring during irradiation of TiO{sub 2} thin films by means of KrF excimer laser, we have performed infrared time resolved reflectivity measurements. This experimental investigation revealed modifications of the heating/cooling cycle as a function of the fluence (F). These modifications start appearing for a fluence value of about {approx}0.25 J/cm{sup 2} which is associated with the melting threshold of the film. Additionally, we have solved numerically the heat equation of the system with specific boundary conditions. From these calculations, we have established the thermal history of the film during the 25 ns irradiation pulse. The data reveal that a part of the medium liquefies around a fluence of 0.23 J/cm{sup 2} in good agreement with the experimental data.

OSTI ID:
22089241
Journal Information:
Journal of Applied Physics, Vol. 111, Issue 12; Other Information: (c) 2012 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English