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Title: Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones

Journal Article · · Crystallography Reports
 [1]; ;  [1];  [2]; ;  [3];  [4]
  1. Academy of Sciences of Moldova, Institute of Applied Physics (Moldova, Republic of)
  2. National Research Council, Institute of Materials for Electronics and Magnetism (Italy)
  3. Moldova State University (Moldova, Republic of)
  4. Autonomous University of San Luis Potosi (Mexico)

New thiosemicarbazones-2-formyl-6-methylpyridine 4-phenylthiosemicarbazone (I) and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazone hydrate (II)-were synthesized and their structures were determined. Molecules I and II are nonplanar, the phenyl moiety at the terminal nitrogen atom being rotated by 19.9 Degree-Sign and 39.5 Degree-Sign , respectively. The water molecule is the main factor determining the crystal packing of molecules II.

OSTI ID:
22054338
Journal Information:
Crystallography Reports, Vol. 56, Issue 1; Other Information: Copyright (c) 2011 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
Country of Publication:
United States
Language:
English