Synthesis and crystal structure of [(C{sub 7}H{sub 10}N){sub 2}]{sup 2+} [Sb{sub 2}Cl{sub 8}]{sup 2-1}
Journal Article
·
· Crystallography Reports
- Zhejiang University of Technology, College of Pharmaceutical Sciences (China)
- Hangzhou Normal University, College of Material Chemistry and Chemical Engineering (China)
The reaction of 2,6-dimethylpyridine with SbCl{sub 3} and HCl affords the title compound, the structure of which is ascertained by X-ray diffraction. The unit cell consists of one bridged Sb{sub 2}Cl{sub 8}{sup 2-} anion and two 2,6-dimethylpyridinium cations. The trivalent antimony ion is bonded not only directly to chlorine anions, but also is coordinated with chlorine anions by secondary bonds. In the crystal, there exists infinite coordinated chains of [Sb{sub 2}Cl{sub 8}]{sub n}{sup 2n-} anions running along the a axis, which link 2,6-dimethylpyridinium cations by N-H-Cl hydrogen bonds.
- OSTI ID:
- 22054046
- Journal Information:
- Crystallography Reports, Vol. 55, Issue 7; Other Information: Copyright (c) 2010 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
Similar Records
Crystal structure of the new compound Pb{sub 3+x}Sb{sub 3-x}S{sub 7-x}Cl{sub 1+x}(x{approx}0.45): The homologous series Pb{sub (2+2N)}(Sb,Pb){sub (2+2N)}S{sub (2+2N)}(S,Cl){sub (4+2N)}Cl{sub N} and its polychalcogenide derivatives (N=1-3)
Synthesis and structures of zirconium complexes [Et{sub 2}H{sub 2}N]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}, [Me{sub 3}NCH{sub 2}Ph]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}•MeCN, [Ph{sub 3}PC{sub 6}H{sub 4}(CHPh{sub 2}-4)]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}•2 MeCN, and [Ph{sub 4}Sb]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}
Single crystal X-ray diffraction studies on [(CH{sub 3}){sub n}NH{sub 4-n}]{sub 3}[Sb{sub 2}Cl{sub 9}] (n=2, 3) chloroantimonates(III) in their low-temperature ferroelectric phases-structures and phase transitions
Journal Article
·
Tue Apr 15 00:00:00 EDT 2008
· Journal of Solid State Chemistry
·
OSTI ID:22054046
+2 more
Synthesis and structures of zirconium complexes [Et{sub 2}H{sub 2}N]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}, [Me{sub 3}NCH{sub 2}Ph]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}•MeCN, [Ph{sub 3}PC{sub 6}H{sub 4}(CHPh{sub 2}-4)]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}•2 MeCN, and [Ph{sub 4}Sb]{sup +}{sub 2}[ZrCl{sub 6}]{sup 2–}
Journal Article
·
Tue Jan 15 00:00:00 EST 2019
· Russian Chemical Bulletin
·
OSTI ID:22054046
Single crystal X-ray diffraction studies on [(CH{sub 3}){sub n}NH{sub 4-n}]{sub 3}[Sb{sub 2}Cl{sub 9}] (n=2, 3) chloroantimonates(III) in their low-temperature ferroelectric phases-structures and phase transitions
Journal Article
·
Fri Jul 15 00:00:00 EDT 2005
· Journal of Solid State Chemistry
·
OSTI ID:22054046