Crystal structure of the binary complex of cobalt and zinc chlorides with carbamide [Co(OCN{sub 2}H{sub 4}){sub 5}(H{sub 2}O)][ZnCl{sub 4}]
Journal Article
·
· Crystallography Reports
- Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)
- National Academy of Sciences of Kyrgyzstan, Institute of Chemistry and Chemical Technology (Kyrgyzstan)
Mixed single crystals of [Co(OCN{sub 2}H{sub 4}){sub 5}(H{sub 2}O)][ZnCl{sub 4}] were grown by the isothermal evaporation of an aqueous solution. The crystal structure of this complex was established by X-ray diffraction (R = 0.052 based on 7003 reflections). The crystals consist of [Co(OCN{sub 2}H{sub 4}){sub 5}(H{sub 2}O)]{sup 2+} cations containing Co atoms in an octahedral coordination and [ZnCl{sub 4}]{sup 2-}] anions containing Zn atoms in a tetrahedral coordination. The carbamide molecules are involved in both intramolecular and interionic hydrogen bonds. The H{sub 2}O molecule forms hydrogen bonds with the anions.
- OSTI ID:
- 22051224
- Journal Information:
- Crystallography Reports, Vol. 55, Issue 2; Other Information: Copyright (c) 2010 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
- Country of Publication:
- United States
- Language:
- English
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