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Title: Texture and microstructure evolution in single-phase Ti{sub x}Ta{sub 1-x}N alloys of rocksalt structure

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.3622585· OSTI ID:22038676
 [1];  [1];  [2]
  1. Institut Prime, CNRS-Universite de Poitiers-ENSMA, UPR 3346, Departement Physique et Mecanique des Materiaux, SP2MI, Teleport 2, Bd M et P Curie, F-86962 Chasseneuil-Futuroscope (France)
  2. Department of Materials Science and Engineering, University of Ioannina, GR-45100 Ioannina (Greece)

The mechanisms controlling the structural and morphological features (texture and microstructure) of ternary transition metal nitride thin films of the Ti{sub x}Ta{sub 1-x}N system, grown by various physical vapor deposition techniques, are reported. Films deposited by pulsed laser deposition, dual cathode magnetron sputtering, and dual ion beam sputtering have been investigated by means of x-ray diffraction in various geometries and scanning electron microscopy. We studied the effects of composition, energetic, and kinetics in the evolution of the microstructure and texture of the films. We obtain films with single and mixed texture as well as films with columnar ''zone-T'' and globular type morphology. The results have shown that the texture evolution of ternary transition metal nitrides as well as the microstructural features of such films can be well understood in the framework of the kinetic mechanisms proposed for their binary counterparts, thus giving these mechanisms a global application.

OSTI ID:
22038676
Journal Information:
Journal of Applied Physics, Vol. 110, Issue 4; Other Information: (c) 2011 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English

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