FORMATION OF PEPTIDE BONDS IN SPACE: A COMPREHENSIVE STUDY OF FORMAMIDE AND ACETAMIDE IN Sgr B2(N)
- Departments of Chemistry and Astronomy, University of Arizona, Tucson, AZ 85721 (United States)
- Institute of Radio Astronomy of the National Academy of Sciences Ukraine, Chervonopraporna 4, 61002 Kharkov (Ukraine)
Extensive observations of acetamide (CH{sub 3}CONH{sub 2}) and formamide (NH{sub 2}CHO) have been conducted toward Sgr B2(N) at 1, 2, and 3 mm using the Submillimeter Telescope (SMT) and the 12 m antenna of the Arizona Radio Observatory. Over the frequency range 65-280 GHz, 132 transitions of acetamide have been observed as individual, distinguishable features, although in some cases they are partially blended. The unblended transitions in acetamide indicate V{sub LSR} = 63.2 {+-} 2.8 km s{sup -1} and {Delta}V{sub 1/2} = 12.5 {+-} 2.9 km s{sup -1}, line parameters that are very similar to that of formamide (NH{sub 2}CHO) and other organic species in Sgr B2(N). For formamide, 79 individual transitions were identified over the same frequency region. Rotational diagram analyses indicate the presence of two components for both species in Sgr B2(N). For acetamide, the colder component (E{sub u} < 40 K) exhibits a rotational temperature of T{sub rot} = 17 {+-} 4 K and a column density of N{sub tot} = 5.2 {+-} 3.5 Multiplication-Sign 10{sup 13} cm{sup -2}; the higher energy component has T{sub rot} = 171 {+-} 4 K and N{sub tot} = 6.4 {+-} 4.7 Multiplication-Sign 10{sup 14} cm{sup -2}. In the case of formamide, T{sub rot} = 26 {+-} 4 K and N{sub tot} = 1.6 {+-} 0.7 Multiplication-Sign 10{sup 14} cm{sup -2} for the colder component with T{sub rot} = 134 {+-} 17 K and N{sub tot} = 4.0 {+-} 1.2 Multiplication-Sign 10{sup 14} cm{sup -2} for the warmer region. The fractional abundances of acetamide are f (H{sub 2}) = 1.7 Multiplication-Sign 10{sup -11} and 2.1 Multiplication-Sign 10{sup -10} for the cold and warm components, and in formamide, f (H{sub 2}) = 5.3 Multiplication-Sign 10{sup -11} and 1.3 Multiplication-Sign 10{sup -10}. The similarity between the abundances and distributions of CH{sub 3}CONH{sub 2} and NH{sub 2}CHO suggests a synthetic connection. The abundance of acetamide, moreover, is only a factor of three lower than that of formaldehyde, and very similar to acetaldehyde and ketene. CH{sub 3}CONH{sub 2} is therefore one of the most abundant complex organic species in Sgr B2(N), and could be a possible source of larger peptide molecules, as opposed to amino acids.
- OSTI ID:
- 22004524
- Journal Information:
- Astrophysical Journal, Vol. 743, Issue 1; Other Information: Country of input: International Atomic Energy Agency (IAEA); ISSN 0004-637X
- Country of Publication:
- United States
- Language:
- English
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