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Title: Evaluation of lithium as a toxicant and the modifying effect of sodium

Conference ·
OSTI ID:218464
; ;  [1]
  1. Oak Ridge National Lab., TN (United States)

Routine compliance tests conducted for a groundwater treatment facility at the Y-12 Plant on the Department of Energy`s (DOE) Oak Ridge Reservation (ORR), TN, showed that the effluent was acutely toxic to Ceriodaphnia dubia and fathead minnow (Pimephales promelas) larvae. An evaluation of suspected contaminants revealed that increased toxicity coincided with increased concentrations of lithium. Lithium is a light, strong metal that is used in DOE operations, including fusion weapons and fission reactors. Little has been published about lithium toxicity. Toxicity tests were conducted with fathead minnows and C. dubia using lithium chloride and lithium tetraborate. Dilute mineral water (DMW) or the receiving stream water (East Fork Poplar Creek) was used as the dilution water in the toxicity evaluation. A concentration of 1 mg Li/L in DMW reduced the survival of both test species; 0.5 mg Li/L in DMW reduced C. dubia reproduction and minnow growth. Sodium appears to influence the toxicity of Li; the metal was six times more toxic in the low-sodium DMW than in stream water containing 30 mg Na/L. Tests with LiCl in combination with NaCl and NA{sub 2}SO{sub 4} demonstrated that the presence of sodium reduced the toxicity of Li to C. dubia. In laboratory tests with a snail (Elimia clavaeformis) common on the ORR, the feeding rate declined in 0.15 mg Li/L. Because Li has also been demonstrated to be toxic to several plant species, tests with LiCi were also conducted using buttercrunch lettuce (Lactuca saliva). The EC{sub 50} for seed growth after 8 d incubation was 37.5 mg Li/L. These findings are significant because of widespread industrial use and potential accumulation of Li in soils.

OSTI ID:
218464
Report Number(s):
CONF-9511137-; ISBN 1-880611-03-1; TRN: 96:010727
Resource Relation:
Conference: 2. Society of Environmental Toxicology and Chemistry (SETAC) world conference, Vancouver (Canada), 5-9 Nov 1995; Other Information: PBD: 1995; Related Information: Is Part Of Second SETAC world congress (16. annual meeting): Abstract book. Global environmental protection: Science, politics, and common sense; PB: 378 p.
Country of Publication:
United States
Language:
English